About Organic acid energy storage
Nafion®115 membrane (Dupont) was supplied from Sigma-Aldrich. Commercially available chemicals were used without further purification. All reactions using air/moisture sensitive reagents were performed in flam.
The synthesis of 2,2′,3,3′-tetrahydroxy-9,9′-spirobifluorene (SBF) monomer precursors to.
A solution of TMSCS (230 mM) in CDCl3 (100 µL) was added to a solution of 2,2′,3,3′-tetramethoxy-9,9’-spirobifluorene (SBF-OMe, 46 mM) in CDCl3 (400 µL) at 273 K. The samp.
The sulfonation of PIM-SBF polymer was achieved using trimethylsilyl chlorosulfonate (TMSCS) as the sulfonation agent as presented in Supplementary Fig. 2. Detailed synth.
The redox-active molecule 2,6-DPPAQ was synthesized following a reported method51. A mixture of 2,6-dihydroxyanthraquinone (7.80 g, 32.47 mmol), diethyl (3-bromopropyl)pho.
Membrane formation was achieved by dissolving PIM-SBF polymer (0.6 g) in CHCl3 (20 mL) or sPIM-SBF polymer (0.7 g) in DMSO (22 mL), which was then centrifuged (12,0.
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