About Chen liquan talks about energy storage
Li6PS5Cl powder was obtained by mechanically ball milling a stoichiometric mixture of Li2S (Alfa, 99.9%), P2S5 (Macklin, 99%), and LiCl (99.9%, Aladdin) for 20 h at 600 r.p.m. under an argon atmosphere, followe.
The Si anode was prepared by repeated rolling of the mixture of Si and PTFE with a weight.
To prepared the NMC811 electrodes, 79.4 wt% NMC811, 16.9 wt% Li6PS5Cl, 3 wt% VGCF and 0.7 wt% PTFE were first mixed to form a single flake. Subsequently, the flake was hot roll.
XRD was conducted using Cu Kα radiation (λ = 1.54178 Å) over a 2θ range of 10–80° with a step size of 8° min−1; samples were sealed in argon atmosphere via vacuum silicone and cove.
Electronic conductivity of the anode was measured via a voltammetry test using a Zennium Pro Electrochemical Workstation by pressing the anode into Swagelok model cell. The Li diffusi.
All the preparation processes were performed in an argon-filled glovebox (O2 < 0.1 ppm, H2O < 0.1 ppm). And the LiSi alloy anode spontaneously formed during the battery prepa.
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3 FAQs about [Chen liquan talks about energy storage]
Could lithium metal anode 5 solve the energy density bottleneck?
Replacing the flammable and non-aqueous organic liquid electrolyte solutions with more thermal-stable solid electrolytes (SEs) could overcome the safety issues and break through the energy density bottleneck by coupling with lithium metal anode 5.
How do dopants contribute to the cycle stability of LiCoO2?
These dopants contribute through different mechanisms and synergistically promote the cycle stability of LiCoO2 at 4.6 V. LiCoO2 is a widely used cathode material in Li-ion batteries for applications such as portable electronics.
How does electrochemical cycling affect the stability of Li plating/stripping?
Electrochemical cycling involves mass and charge transfer at SE/Li interface and hence causes changes in interfacial morphology, which in turn affects the stability of Li plating/stripping. It is believed that Li diffusion in bulk Li metal is limited by the diffusion of Li vacancies.
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